The kinetics of the free-radical reaction of asymmetric hydrazines (R 1R2NNH2), with hydroxyl radicals and hydrated electrons were investigated as a function of substituent chain length and morphology in aqueous solution. In addition, these same radical kinetics were established for two different commercial dissolved organic matter compounds, Suwannee River Fulvic Acid (SRFA) and Elliot Soil Humic Acid (ESHA) as a model of real-world waters. Lastly, the kinetics of two hydrazine target molecules, 1-aminopiperidine and 1-aminohomopiperidine, were then used to investigate the role of model dissolved organic matter species concentration as a mimic of real-world water contaminant removal using advanced oxidation processes.
|School:||California State University, Long Beach|
|School Location:||United States -- California|
|Source:||MAI 49/05M, Masters Abstracts International|
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