The development of copper(II) promoted and catalyzed difunctionalization reactions is discussed. These methods synthesize a variety of complex nitrogen heterocycles in enantioenriched form. Furthermore, attempts to apply this chemistry toward the total synthesis of Spirotryprostatin A is described.
|Advisor:||Chemler, Sherry R.|
|Commitee:||Detty, Michael, Diver, Steven T., Watson, David|
|School:||State University of New York at Buffalo|
|School Location:||United States -- New York|
|Source:||DAI-B 70/05, Dissertation Abstracts International|
|Keywords:||Aminooxygenation, Carboamination, Copper(II), Olefins, Spirotryprostatin|
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