Dissertation/Thesis Abstract

The author has requested that access to this graduate work be delayed until 2020-01-12. After this date, this graduate work will be available on an open access basis.
Synthesis and Characterization of Some Novel Dinitrosyl Diphosphine Iron Complexes
by Manandhar, Rachana, M.S., Southern Illinois University at Edwardsville, 2017, 54; 10686177
Abstract (Summary)

Dinitrosyl iron complexes (DNICs) contribute to the biological action of nitric oxide (NO) including the ability to store and transfer NO. Therefore, it is important to assess how ancillary ligands bound to the metal affect the fundamental properties of the Fe(NO)2 group. With this project, several new {Fe(NO)2}10 dinitrosyl iron compounds have been prepared by replacement of CO in Fe(NO)2(CO)2 with chelating diphosphine ligands. Attempts to synthesize new functionalized dinitrosyl diphosphine complexes via Aza Michael addition were also carried out. All of the newly prepared DNICs were characterized using FT-IR, ATR-IR and 31P{1H} NMR spectroscopy.

Indexing (document details)
Advisor: Jones, Myron W.
Commitee: Lu, Yun, Sumita, Mina
School: Southern Illinois University at Edwardsville
Department: Chemistry
School Location: United States -- Illinois
Source: MAI 57/02M(E), Masters Abstracts International
Subjects: Chemistry
Publication Number: 10686177
ISBN: 978-0-355-60382-8
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