The present work is on the reaction of a chelating diphosphine dinitrosyl iron complex (DNIC) with the amines: aniline, p-fluoro aniline and p-methyl aniline in three different reactions. The aim was to determine then ability of the amine to attack the phosphine disubstituted DNIC via an aza-Michael addition reaction breaking the double bond. The synthetic route described in this thesis employs inexpensive and readily available amines. The phosphine disubstituted DNIC had first to be synthesized using literature methods. The three target products have not been reported before and each reaction target is reached after one synthetic step.
|Advisor:||Jones, Myron W.|
|Commitee:||Lu, Yun Y. L., Voss, Eric E. V.|
|School:||Southern Illinois University at Edwardsville|
|School Location:||United States -- Illinois|
|Source:||MAI 56/03M(E), Masters Abstracts International|
|Subjects:||Molecular chemistry, Physical chemistry|
|Keywords:||Alajmi, Alyami, Bakhitah, Latin, Lauren, Marzouq|
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